| dc.contributor.author | Postigo, Al | |
| dc.contributor.author | Kopsov, Sergey | |
| dc.contributor.author | Zlotsky, Simon S. | |
| dc.contributor.author | Ferreri, Carla | |
| dc.contributor.author | Chatgilialoglu, Chryssostomos | |
| dc.date.accessioned | 2014-07-25T21:22:57Z | |
| dc.date.available | 2014-07-25T21:22:57Z | |
| dc.date.issued | 2009 | |
| dc.identifier.uri | http://repositorio.ub.edu.ar/handle/123456789/2726 | |
| dc.description.abstract | The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and water-soluble substrates. Different initiation methods to accomplish the radical-induced hydrosilylation reaction of C−C multiple bonds in water with (Me3Si)3SiH are presented. In the thermal decomposition of azo compounds, the system comprising substrate, silane, and azo-initiator (ACCN) mixed in aqueous medium at 100 °C worked well for both hydrophilic and hydrophobic substrates, with the only variation that the amphiphilic thiol HOCH2CH2SH was also needed in the case of the water-soluble compounds. | es_ES |
| dc.language.iso | en | es_ES |
| dc.publisher.Editor | Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación | |
| dc.relation.ispartofseries | Organometallics;2009, 28 (11), pp 3282–3287 | |
| dc.subject | Hydrosilylation | es_ES |
| dc.subject | Multiple Bonds | es_ES |
| dc.subject | Radical Initiation Step | es_ES |
| dc.subject | hidrosililación | es_ES |
| dc.subject | Iniciación por radicales Paso | es_ES |
| dc.subject | Enlaces múltiples | es_ES |
| dc.title | Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step | es_ES |
| dc.type | Article | es_ES |
