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Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(2010)
The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
(Me3Si)3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water
(2010)
Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different ...
Radiation Chemical Studies of Methionine in Aqueous Solution: Understanding the Role of Molecular Oxygen
(2010)
The oxidation of methionine is an important reaction in the biological milieu. Despite a few decades
of intense studies, several fundamental aspects remain to be defined. We have investigated in detail the
γ-radiolysis ...
Streamlining free radical green chemistry
(2012)
This practical and concise guide showcases the sustainable methods offered by green free radical chemistry and summarizes the fundamental science involved. It discusses free radical chemistry in aqueous systems for synthetic ...
Organic Synthesis in Water Mediated By Silyl Radicals
(2011)
This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...