Now showing items 1-2 of 2

    • Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation 

      Calandra, Julia; Postigo, Al; Russo, Diana; Sbarbati Nudelman, Norma; Tereñas, Juan José (Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)
      The classical radical-based hydrosilylation reaction of organic compounds bearing C C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic substrates. ...
    • Organic Synthesis in Water Mediated By Silyl Radicals 

      Barata-Vallejo, Sebastian; Sbarbati Nudelman, Norma; Postigo, Al (Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2011)
      This account is focused on highlighting the recent advances on synthetically-useful organic reactions employing siliconcentered radicals in water, and presenting new reactions in water, mediated by silyl radicals. In doing ...