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(Me3Si)3SiH-Mediated Intermolecular Radical Perfluoroalkylation Reactions of Olefins in Water
Barata-Vallejo, Sebastián; Postigo, Al (Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2010)Perfluoroalkyl-substituted compounds are regarded as important components of fluorophors and for the introduction of fluorous tags into organic substrates. Their syntheses in organic solvents are achieved through different ... -
Radiation Chemical Studies of Methionine in Aqueous Solution: Understanding the Role of Molecular Oxygen
Barata-Vallejo, Sebastián; Ferreri, Carla; Postigo, Al; Chatgilialoglu, Chryssostomos (Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2010)The oxidation of methionine is an important reaction in the biological milieu. Despite a few decades of intense studies, several fundamental aspects remain to be defined. We have investigated in detail the γ-radiolysis ...