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Solvent effects on the reactivity of fluorenyl nitrenium ion with DNA-like probes
(2006)
Laser Flash Photolysis (LFP) experiments carried out on 2-azidofluorene in aqueous systems generate 2-fluorenyl nitrenium ion (λmax = 450 nm) which decays with first order rate constant and is quenched with 2′-deoxyguanosine ...
A facile one-pot synthesis of 8-oxo-7,8-dihydro-(2′-deoxy)adenosine in water
(2006)
Reaction of 2-mercaptoethanol with 8-bromo-2′-deoxyadenosine and 8-bromo-adenosine in aqueous solution and in the presence of triethylamine gave the 8-oxo-adenine derivatives in very good yields. Some mechanistic details ...