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Solvent effects on the reactivity of fluorenyl nitrenium ion with DNA-like probes
McClelland, Robert A.; Postigo, Al (Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2006)Laser Flash Photolysis (LFP) experiments carried out on 2-azidofluorene in aqueous systems generate 2-fluorenyl nitrenium ion (λmax = 450 nm) which decays with first order rate constant and is quenched with 2′-deoxyguanosine ...