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Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
Postigo, Al; Kopsov, Sergey; Zlotsky, Simon S.; Ferreri, Carla; Chatgilialoglu, Chryssostomos (Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación, 2009)The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and ... -
Radiation Chemical Studies of Methionine in Aqueous Solution: Understanding the Role of Molecular Oxygen
Barata-Vallejo, Sebastián; Ferreri, Carla; Postigo, Al; Chatgilialoglu, Chryssostomos (Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación, 2010)The oxidation of methionine is an important reaction in the biological milieu. Despite a few decades of intense studies, several fundamental aspects remain to be defined. We have investigated in detail the γ-radiolysis ...